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以富CO2吸收液為汲取液的沼液中水正滲透回收特性研究
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國家自然科學基金項目(52076101)和武漢市知識創(chuàng)新專項(2023020201010108)


Performance of Water Recovery from Biogas Slurry by Forward Osmosis Technology when Adopting CO2-rich Solvent as Draw Solution
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    摘要:

    針對沼氣工程存在的沼液量大難處理問題及沼氣提純的需求,,提出將正滲透技術(shù)與沼氣CO2化學吸收分離耦合,,探究了沼氣CO2化學吸收中的富CO2吸收液作為正滲透汲取液從沼液中回收水及濃縮沼液的可行性,并以沼液濃縮過程中的水通量,、沼液濃縮倍數(shù),、沼液氨氮截留率與吸收劑反向傳質(zhì)通量為指標,考察了汲取液種類,、汲取液濃度與其他操作參數(shù)對正滲透水回收性能的影響,。結(jié)果表明,富CO2吸收液作為汲取液從沼液中回收水并濃縮沼液具有可行性,,且隨著汲取液濃度,、流量和溫度的增加,沼液中水向汲取液的傳質(zhì)通量增加,,沼液濃縮倍數(shù)也相應增加,,但沼液中氨氮截留率下降,同時汲取液中的吸收劑溶質(zhì)向沼液的反向傳質(zhì)通量也增加,。當采用濃度2.5mol/L,、CO2負荷0.5mol/mol的富CO2甘氨酸鉀溶液作為汲取液,汲取液溫度為70℃,、流速為150mL/min,、沼液室溫及流速為150mL/min時,采用正滲透技術(shù)從沼液中回收水的初始通量達8.05L/(m2·h),,經(jīng)過4h運行后,,沼液濃縮倍數(shù)為1.18,氨氮截留率為84.13%,,反向吸收劑通量僅為2.94g/(m2·h),。

    Abstract:

    In the biogas project, determining how to treat the biogas slurry with large volume is one of big issues. Additionally, biogas upgrading is always required for increasing the heat value of biogas. A concept was proposed by coupling the water recovery using forward osmosis and CO2 chemical absorption, in which the CO2-rich solvent from CO2 chemical absorption process was adopted as the draw solution to recover water from biogas slurry in forward osmosis. The feasibility of water recovery from biogas slurry by using CO2-rich solvent as the draw solution in addition to concentrating the biogas slurry was experimentally investigated. In terms of the water flux, concentration ratio of biogas slurry, rejection ratio of ammonia nitrogen and CO2 absorbent transfer flux from the draw solution to biogas slurry, effects of the type and mass fraction of draw solution and other key operation parameters on water recovery performance in forward osmosis were explored. Results showed that CO2-rich solvent can be adopted as the draw solution to successfully reclaim water from biogas slurry and simultaneously concentrate the biogas slurry in forward osmosis. Additionally, the water flux transferred from biogas slurry from the draw solution increases with the mass fraction, flow rate and temperature of draw solution. Correspondingly, the concentration ratio of biogas slurry was increased, however, the rejection ratio of ammonia nitrogen in biogas slurry was decreased and the absorbent transfer flux of CO2 absorbent was increased. When the CO2-rich potassium glycinate with 2.5mol/L and 0.5mol/mol CO2 loading was adopted as the draw solution in the forward osmosis, the initial water flux from biogas slurry was about 8.05L/(m2·h) at the conditions of 70℃ and 150mL/min for draw solution, and ambient temperature and 150mL/min for biogas slurry. After 4h operation, the concentration ratio and ammonia nitrogen rejection ratio of biogas slurry can reach 1.18 and 84.13%, respectively. Notably, the CO2 absorbent transfer flux was only 2.94g/(m2·h). The research result may provide a technical support for concentrating biogas slurry and recovering water from biogas slurry.

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汪洋,石明菲,賀清堯,晏水平.以富CO2吸收液為汲取液的沼液中水正滲透回收特性研究[J].農(nóng)業(yè)機械學報,2024,55(6):317-324. WANG Yang, SHI Mingfei, HE Qingyao, YAN Shuiping. Performance of Water Recovery from Biogas Slurry by Forward Osmosis Technology when Adopting CO2-rich Solvent as Draw Solution[J]. Transactions of the Chinese Society for Agricultural Machinery,2024,55(6):317-324.

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  • 收稿日期:2023-10-30
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  • 在線發(fā)布日期: 2024-06-10
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