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Ni-Zn/玄武巖催化劑生物質(zhì)催化氣化實驗
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國家自然科學(xué)基金地區(qū)科學(xué)基金項目(51768054、51764046),、內(nèi)蒙古自治區(qū)自然科學(xué)基金面上項目(2017MS(LH)0524),、內(nèi)蒙古自治區(qū)教育科學(xué)研究“十三五”規(guī)劃項目(NGJGH2017089)和校企合作項目(2018073)


Experiment on Biomass Catalytic Gasification of Ni-Zn/Basalt Catalyst
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    摘要:

    采用一步水熱法原位合成工藝制備了Ni-Zn/玄武巖復(fù)合催化劑,,對催化劑微觀形貌和表面元素分布進行了表征,。以松木顆粒為原料,、水蒸氣為氣化劑,,采用下吸式管式氣化爐實驗平臺,,研究了Ni-Zn/玄武巖復(fù)合材料在不同溫度下高溫蒸汽的催化氣化效果,,通過考察氣體組分變化,,探討Ni-Zn/玄武巖復(fù)合催化劑催化性能隨溫度變化的規(guī)律,并與無催化劑和以白云石為催化劑的催化性能進行實驗對比,。實驗結(jié)果表明:水熱反應(yīng)溫度為130℃,,反應(yīng)時間為12h時,Ni,、Zn能很好地負載在玄武巖纖維表面,;與不加催化劑和加入白云石催化劑相比,Ni-Zn/玄武巖復(fù)合催化劑氣化溫度在950℃時催化效率明顯提升,,氫氣體積分數(shù)增加明顯,,分別由無催化劑時的58.6%、加入白云石催化劑時的50.02%升高至63.28%,。

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    The Ni-Zn/basalt composite catalyst was prepared by the method of in-situ hydrothermal. The microstructure and surface element distribution of the catalyst was characterized. Taking the pine particles as raw materials and water vapor as the gasification agent, and the test system platform of the lower suction tubular gasifier was adopted. Ni-Zn/basalt composite material was studied at different temperatures of high temperature steam catalytic gasification effect. Through investigating the changes in gas composition, the variation laws of the catalytic properties of Ni-Zn/basalt composite catalyst with temperature variation were studied. The result was compared with the contrast experiments with no catalyst and dolomite as catalyst performance. The experimental results showed that Ni and Zn could be well supported on the surface of basalt fiber with the reaction temperature of 130℃ and the reaction time of 12h. Compared with no catalyst and adding dolomite catalyst, Ni-Zn/basalt composite catalyst gasification temperature at 950℃, the catalytic efficiency was improved significantly and the hydrogen volume fraction was significantly increased. The hydrogen volume fraction was increased to 63.28% while without catalyst, the hydrogen volume fraction was only 58.6% and with dolomite catalyst, the hydrogen volume fraction was 50.02%. It can be seen that Ni-Zn/basalt composite catalyst has high efficiency in the catalytic gasification reaction of pine sawdust. It can provide theoretical and experimental basis for further improving biomass gasification technology.

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牛永紅,田一鳴. Ni-Zn/玄武巖催化劑生物質(zhì)催化氣化實驗[J].農(nóng)業(yè)機械學(xué)報,2019,50(6):331-337. NIU Yonghong, TIAN Yiming. Experiment on Biomass Catalytic Gasification of Ni-Zn/Basalt Catalyst[J]. Transactions of the Chinese Society for Agricultural Machinery,2019,50(6):331-337.

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  • 收稿日期:2018-12-18
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  • 在線發(fā)布日期: 2019-06-10
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