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玉米秸稈纖維素的磷酸結(jié)合堿性過氧化氫分離
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國家自然科學(xué)基金項(xiàng)目(31671572)和中央高校基本科研業(yè)務(wù)費(fèi)專項(xiàng)資金項(xiàng)目(2018TC027)


Separation of Corn Stover Cellulose by Phosphoric Acid Combined with Alkaline Hydrogen Peroxide
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    傳統(tǒng)玉米秸稈纖維素分離工藝中,一般采用硫酸等強(qiáng)酸進(jìn)行處理,存在酸腐蝕性強(qiáng)及堿消耗量大等問題。基于此,研究以磷酸預(yù)處理結(jié)合堿性過氧化氫的處理工藝,探究處理過程中玉米秸稈纖維素、半纖維素及木質(zhì)素質(zhì)量分?jǐn)?shù)的變化。通過單因素試驗(yàn)優(yōu)化得到適宜工藝為:磷酸處理溫度150℃,處理時(shí)間1.5h,磷酸質(zhì)量分?jǐn)?shù)1.67%,氫氧化鈉質(zhì)量分?jǐn)?shù)1.0%,過氧化氫質(zhì)量分?jǐn)?shù)2.0%,處理溫度50℃,處理時(shí)間3h,在此條件下制備的玉米秸稈纖維素得率達(dá)89.02%,半纖維素去除率達(dá)93.25%,木質(zhì)素去除率達(dá)95.18%,纖維素質(zhì)量分?jǐn)?shù)達(dá)90.19%,同時(shí)在稀磷酸處理過程獲得的濾液中能得到高副加值產(chǎn)物木糖、阿拉伯糖以及糠醛,半纖維素的回收率高達(dá)93.81%。通過FTIR、SEM、AFM和XRD等測試分析發(fā)現(xiàn),玉米秸稈經(jīng)過磷酸處理后能有效去除半纖維素,堿性過氧化氫處理能脫除木質(zhì)素組分,兩步處理過程中秸稈纖維素晶型無變化,但是結(jié)晶度顯著提高,熱穩(wěn)定性增強(qiáng)。

    Abstract:

    In the traditional corn stover cellulose separation process, it is generally treated with strong acid such as sulfuric acid, which has strong acid corrosion and large alkali consumption. Based on this, the treatment of phosphoric acid pretreatment combined with alkaline hydrogen peroxide was studied, and the changes of cellulose, hemicellulose and lignin contents in corn stover during the treatment were investigated. The optimum process was optimized by single factor experiments: phosphoric acid treatment temperature of 150℃, treatment time of 1.5h, phosphoric acid concentration of 1.67%, sodium hydroxide concentration of 1.0%, hydrogen peroxide concentration of 2.0%, treatment temperature of 50℃, treatment time of 3h, the yield of cellulose obtained from corn stalk under this condition was 89.02%, hemicellulose removal rate was 93.25%, lignin removal rate was 95.18%, the purity of the cellulose reached 90.19%. Meanwhile, a high secondary value product can be obtained in the filtrate obtained by the phosphoric acid treatment process, including xylose of 68.72%, arabicose of 65.14% and furfural of 30.25%. The characterization of the raw materials and the treated materials showed that the phosphoric acid treatment can effectively remove the hemicellulose and the alkaline hydrogen peroxide treatment can remove lignin components. The cellulose crystal form was not changed, but the crystallinity was increased significantly, and the thermal stability was increased. In addition to obtaining highpurity cellulose, the use of this preacid postbase treatment can also give high added value as a by-product of xylose and furfural. The research laid a theoretical foundation for the efficient utilization of corn stover cellulose.

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肖衛(wèi)華,趙廣路,農(nóng)植嵩,杜澤宇,呂雪.玉米秸稈纖維素的磷酸結(jié)合堿性過氧化氫分離[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2019,50(4):298-308. XIAO Weihua, ZHAO Guanglu, NONG Zhisong, DU Zeyu, Lü Xue. Separation of Corn Stover Cellulose by Phosphoric Acid Combined with Alkaline Hydrogen Peroxide[J]. Transactions of the Chinese Society for Agricultural Machinery,2019,50(4):298-308.

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  • 收稿日期:2018-10-15
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  • 在線發(fā)布日期: 2019-04-10
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