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生物油重質油醇類添加劑提質研究
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國家自然科學基金項目(51706040),、黑龍江省青年科學基金項目(QC2015049)、東北農業(yè)大學博士基金項目(2012RCB97),、黑龍江省教育廳科學技術研究項目(12531002)和黑龍江省留學回國人員擇優(yōu)資助項目


Heavy Composition of Bio-oil Upgrading by Alcohol Additives
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    摘要:

    通過加入不同質量分數(5%~25%)的甲醇,、乙醇、辛醇及其混合醇對松子殼熱解重質油進行提質研究,,考察醇添加劑對重質油理化特性影響及其存儲穩(wěn)定性,。研究發(fā)現加入醇添加劑超聲處理后能顯著降低重質油的粘度,、含水率和pH值,并提高其熱值,;同時使多環(huán)芳烴,、酮類等物質含量降低,脂肪烴,、芳香烴等含量增加,。混合醇處理重質油的品質更好,,存儲56d后性質仍較穩(wěn)定,,粘度和含水率隨儲存時間延長稍有增加。加入甲辛醇56d后重質油的粘度為980mPa·s,,含水率為21.02%,,增長速率僅均為原始重質油的一半;且添加量越高,,油的熱值越高,,添加量25%時熱值為32.66MJ/kg。但從熱重分析發(fā)現甲辛醇添加量為20%時燃燒性能最好,,其燃燒段的失重速率最大并且燃燒后的灰分最少,。

    Abstract:

    Bio-oil is the main product of biomass pyrolysis, which is considered as a promising replacing fuel for fossil oil. But the high oxygen, high viscosity, low heat value and poor stability of bio-oil make it difficult to apply directly. Thus study on the improvement of bio-oil quality is very necessary. Different mass fractions (5%~25%) of methanol, ethanol, octanol and its two mixed alcohols were used to improve the heavy oil quality which was pyrolysed from pine nut. The physical and chemical properties and storage time of heavy oil with alcohol additive were investigated. The results showed that the addition of alcohol additives could significantly reduce the viscosity, water content and pH value of heavy oil, and enhance its heat value. Simultaneously, the contents of phenols, polycyclic aromatic hydrocarbons and ketones in the heavy oil were decreased, and the contents of aliphatic hydrocarbons, aromatic hydrocarbons and alcohols were increased. The heavy oil adding mixed alcohol showed a better stability, and its viscosity and water content were only increased slightly after 56d. After adding methyl-octanol mixture and stored for 56d, the viscosity of the heavy oil was 980mPa·s, and water content was 21.02%. The growth rate was only a half of the original heavy oil. With the increase of methyl-octanol mixture additive amount, the heat value of heavy oil was increased. When the addition amount was 25%, the heat value was 32.66MJ/kg. However, it was found that the combustion performance was the best when adding 20% of methyl-octanol mixture;the weight loss rate of combustion section was the largest and the amount of ash after combustion was minimal.

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秦麗元,賈月雯,魏曉莉,蔣恩臣.生物油重質油醇類添加劑提質研究[J].農業(yè)機械學報,2017,48(11):324-329. QIN Liyuan, JIA Yuewen, WEI Xiaoli, JIANG Enchen. Heavy Composition of Bio-oil Upgrading by Alcohol Additives[J]. Transactions of the Chinese Society for Agricultural Machinery,2017,48(11):324-329.

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  • 收稿日期:2017-05-07
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  • 在線發(fā)布日期: 2017-11-10
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