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生物炭吸附水體中重金屬機(jī)理與工藝研究進(jìn)展
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國(guó)家自然科學(xué)基金項(xiàng)目(31271611)


Review of Biochar as Adsorbent for Aqueous Heavy Metal Removal
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    摘要:

    生物炭因其良好的表面特性和孔隙結(jié)構(gòu),廣泛的原料來源和廣闊的產(chǎn)業(yè)化發(fā)展前景,已成為當(dāng)今環(huán)境,、農(nóng)業(yè)和能源等領(lǐng)域的研究熱點(diǎn),。針對(duì)生物炭對(duì)水體重金屬的吸附研究,本文基于生物炭原料和制備工藝的多樣性,,綜合分析了國(guó)內(nèi)外生物炭重金屬吸附機(jī)理的研究成果,,詳細(xì)闡述、分析了5種吸附作用機(jī)制(物理吸附,、靜電作用,、離子交換、絡(luò)合反應(yīng)和化學(xué)沉淀)及其相關(guān)表征手段,;同時(shí)評(píng)述了吸附工藝條件和重金屬種類對(duì)生物炭吸附重金屬的影響,;指出生物炭重金屬吸附領(lǐng)域未來的研究中,應(yīng)開展針對(duì)重金屬吸附的生物炭原料特性及吸附產(chǎn)物的多維,、微納尺度表征方法研究,。

    Abstract:

    Biochar has a bright prospect due to its good surface properties, pore structure and broad raw materials of its production. It has already been a hotspot in the fields of environment, agriculture and energy. It can be produced from a variety of biomass feedstock, such as agricultural residues, manures, wood, bone and so on, under oxygen-limited conditions. It has great potentials for heavy metal remediation and waste water treatment due to its unique properties, low price, easy processing and wide range of preparation material. The existing literature was incorporated to understand the overall sorption research of heavy metals on biochar adsorbents. However, there was still lack of information on the roles of different sorption mechanisms for biochar. The effects of feedstock materials and pyrolysis temperature on biochar characteristics and metal adsorption capacity were discussed. The interaction mechanisms between biochar and heavy metals, such as ion exchange, complexation, physical sorption, precipitation and electrostatic interactions were analyzed in detail. The influence of adsorption conditions and heavy metal species on heavy metals adsorbed by biochar was also included. At the end, the future research directions on sorption of heavy metals by biochar were proposed. The review would help to build important theory and methodology foundation for directly controlling production and scientific utilization of biochar.

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韓魯佳,李彥霏,劉賢,韓婭紅.生物炭吸附水體中重金屬機(jī)理與工藝研究進(jìn)展[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2017,48(11):1-11. HAN Lujia, LI Yanfei, LIU Xian, HAN Yahong. Review of Biochar as Adsorbent for Aqueous Heavy Metal Removal[J]. Transactions of the Chinese Society for Agricultural Machinery,2017,48(11):1-11.

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  • 收稿日期:2017-09-21
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  • 在線發(fā)布日期: 2017-11-10
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