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微晶化磷鉀礦粉催化牛糞厭氧消化試驗(yàn)
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國家自然科學(xué)基金項(xiàng)目(51374136),、“十二五”國家科技支撐計(jì)劃項(xiàng)目(2012BAD47B02)、江蘇省科技支撐計(jì)劃項(xiàng)目(BE2013312),、山東省自主創(chuàng)新成果轉(zhuǎn)化重大專項(xiàng)(2013ZHZX1A0307)和無錫市創(chuàng)新基金項(xiàng)目(CBE01G1232)


Application of Microcrystalline Phosphate or Potassium Powder in Anaerobic Digestion of Cattle Manure as Functional Catalysts
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    摘要:

    為了提高沼氣發(fā)酵效率和沼氣產(chǎn)量,,以不同磷鉀礦粉為沼氣發(fā)酵的功能催化劑,探討其對牛糞厭氧發(fā)酵的影響,。試驗(yàn)設(shè)8個處理,,分別為空白處理(CK),添加2.5%(T1),、5.0%(T2),、7.5%(T3)、10.0%(T4)云南微晶化磷礦粉,,5.0%(T5)河南微晶化磷礦粉,,5.0%(T6)云南普通磷礦粉和5.0%(T7)河南微晶化鉀礦粉。試驗(yàn)結(jié)果表明:微晶化磷礦粉量的增加,,顯著地提高了沼氣累積產(chǎn)氣量,。添加75%處理的微晶化磷礦粉發(fā)酵啟動最快,產(chǎn)氣率最高,,CH4體積分?jǐn)?shù)達(dá)62.5%,,VS去除率為61.99%,COD值為4871.4mg/L,,VFA質(zhì)量濃度為469.9mg/L,。當(dāng)微晶化磷礦粉添加量高達(dá)10.0%時,VS沼氣累積產(chǎn)氣量下降到317.63mL/g,。添加7.5%微晶化磷礦粉是改善牛糞厭氧消化的最適添加量。

    Abstract:

    In order to improve the efficiency of biogas fermentation and biogas yields, the influence of different phosphorus potassium powder as the functional catalysts of biogas fermentation on anaerobic fermentation of cow dung was explored. Eight treatments were contained as follows: no addition(CK), the addition of 2.5%(T1), 5.0%(T2), 7.5%(T3), 10.0%(T4)Yunnan microcrystallization phosphate powder, 5.0%(T5)Henan microcrystallization phosphate powder, 5.0%(T6)Yunnan common phosphate powder, and 5.0%(T7)Henan microcrystalline muscovite rock. Results indicated that: with the increase of microcrystalline phosphate powder concentration, the ultimate production of biogas was improved significantly. Adding 7.5% microcrystallization phosphate powder results in the fastest anaerobic fermentation starting, the most biogas yield, and CH4 volume fraction was up to 62.5%, the removal rate of VS reached 61.99%, the chemical oxygen demand (COD) was 4871.4mg/L, the volatile fatty acid (VFA) was 469.9mg/L respectively. As microcrystalline phosphate powder concentration was increased as high as 10.0%, the ultimate accumulative biogas production was inhibited to 317.63mL/g. Adding microcrystallization phosphate powder of 7.5% was considered as the appropriate amount to improve the anaerobic digestion of cow manure. The microcrystalline grinding technology enhanced the nutrient release from the phosphate rock. Thus, it was significant to exploit and utilize the phosphate rock. This study provided a theoretical basis for developing a high efficient biogas catalysts formula and sustainable agriculture.

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張仙梅,云斯寧,杜玉鳳,蓋國勝,楊玉芬,何振全.微晶化磷鉀礦粉催化牛糞厭氧消化試驗(yàn)[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2016,47(5):183-190. Zhang Xianmei, Yun Sining, Du Yufeng, Gai Guosheng, Yang Yufen, He Zhenquan. Application of Microcrystalline Phosphate or Potassium Powder in Anaerobic Digestion of Cattle Manure as Functional Catalysts[J]. Transactions of the Chinese Society for Agricultural Machinery,2016,47(5):183-190.

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  • 收稿日期:2016-02-28
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  • 在線發(fā)布日期: 2016-05-10
  • 出版日期: 2016-05-10
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