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豬糞厭氧消化液兩階段閉式循環(huán)氨脫除工藝優(yōu)化
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國家高技術(shù)研究發(fā)展計(jì)劃(863計(jì)劃)資助項(xiàng)目(2012AA101803)、北京市科技計(jì)劃資助項(xiàng)目(D141100001214001,、D141100001214002)和“十二五”國家科技支撐計(jì)劃資助項(xiàng)目(2012BAD47B02)


Optimization of Ammonia Stripping Process in Two-stage Air-recirculation for Anaerobic Digestion of Pig Manure
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    摘要:

    針對(duì)氨吹脫工藝堿消耗量大,、填料塔填料易結(jié)垢造成壓降,、塔板塔易夾帶霧沫、漏液的技術(shù)缺陷和尾氣氨吸收不完全的問題,,設(shè)計(jì)了兩階段閉式循環(huán)氨脫除工藝,并利用研發(fā)的鼓泡反應(yīng)器進(jìn)行了豬糞厭氧消化液NH+4N脫除的研究。利用響應(yīng)面法優(yōu)化氣流量,、投堿量、氣液比與NH+4N去除率的控制模型,。研究表明:第1階段吹脫厭氧消化液CO2,,消化液pH值1h可從8.03升高到8.86;第2階段在氣流量,、投堿量和氣液比分別為6L/min,、22.13g和3.000時(shí),NH+4N去除率可達(dá)96.78%,;兩階段閉式循環(huán)氨脫除工藝可用于未固液分離的豬糞厭氧消化液NH+4N的脫除,,鼓泡反應(yīng)器可作為該工藝條件下的NH+4N脫除裝置。

    Abstract:

    Ammonia stripping process consumes large amounts of alkali. The packed column is easy to scale and cause pressure drop. The tray tower has the disadvantages of discharge and the large fine droplets loss by entrainment. Besides, the absorption of ammonia nitrogen in the exhaust gas is incomplete. In order to solve the above problems, a twostage airrecirculated stripping process was developed and used in the gasliquid reactor to remove the ammonia nitrogen during anaerobic digestion of pig manure. A mathematical model focusing on the effects of controlling factors (gas flow rate, dose of alkali and gastoliquid ratio) on one response (ammonium nitrogen removal efficiency) was developed and fitted by response surface methodology (RSM). The results showed that the pH value could rise from 803 to 886 in 1h by stripping CO2. The alkalinity of anaerobic digestion was decreased from (8.953±297)mg/L to (8.283±21)mg/L. Stripping carbon dioxide was conducive to reduce the buffer capacity of anaerobic. The ammonium nitrogen removal efficiency could reach 96.78% (dose of lime 22.13g, gas flow rate 6L/min, gastoliquid ratio 3.000). The twostage airrecirculation process could be used to remove and recover ammonium nitrogen in anaerobic digestion of pig manure without pretreatment in this system. The RSM further optimized the twostage airrecirculation ammonia removal process. The developed gasliquid reactor could be used to remove ammonium nitrogen with airrecirculated stripping process.

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劉 良,訾 海,陳新穎,龐昌樂,董仁杰.豬糞厭氧消化液兩階段閉式循環(huán)氨脫除工藝優(yōu)化[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2015,46(9):211-216. Liu Liang, Zi Hai, Chen Xinying, Pang Changle, Dong Renjie. Optimization of Ammonia Stripping Process in Two-stage Air-recirculation for Anaerobic Digestion of Pig Manure[J]. Transactions of the Chinese Society for Agricultural Machinery,2015,46(9):211-216.

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  • 收稿日期:2015-01-29
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  • 在線發(fā)布日期: 2015-09-10
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