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乳化劑與內(nèi)水相鎂鹽濃度對油包水乳液穩(wěn)定性的影響
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國家自然科學基金資助項目(31171648)和“十二五”國家科技支撐計劃資助項目(2012BAD34B03)


Influence of Concentrations of Emulsifier and Magnesium Salt Contained in Internal Phase on Stability of W/O Emulsions
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    摘要:

    研究并討論了內(nèi)水相鎂鹽與疏水乳化劑PGPR對油包水(W/O)乳液穩(wěn)定性的影響,。制備W/O乳液的油水質(zhì)量比為3∶2,,油相中疏水乳化劑聚甘油蓖麻醇酸酯(PGPR)質(zhì)量分數(shù)為0.5%~2.0%,, 水相中MgCl2·6H2O的質(zhì)量分數(shù)為0~12.0%。采用Turbiscan Lab Expert穩(wěn)定性分析儀分析了W/O乳液貯藏14 d過程中的整體穩(wěn)定性,。結(jié)果表明:在14 d貯藏過程中,,液滴的聚沉和沉淀會導(dǎo)致乳液失穩(wěn),。提高疏水乳化劑PGPR和鎂鹽的濃度可提高W/O乳液的穩(wěn)定性,。對W/O乳液的粒徑分布及油水兩相界面特性進行分析,發(fā)現(xiàn)W/O乳液穩(wěn)定的機制在于乳液粒徑的減小以及油水界面張力的降低,。此外,,油水兩相界面粘彈性也在一定程度上改善了乳液穩(wěn)定性,油水界面膜粘彈性隨著鎂鹽濃度的增加呈現(xiàn)先上升后下降的趨勢,。

    Abstract:

    The effect of PGPR and added magnesium chloride hexahydrate on properties of W/O (water-in-oil) emulsions was investigated. W/O emulsions were formulated with 60% oil phase containing 0.5%, 1.0% and 2.0% PGPR and 40% aqueous phase containing magnesium salt at various concentrations from 0 to 12.0%. Stability of these W/O emulsions was studied with Turbiscan Lab Expert during 14-day storage. The result indicated that coalescence and sedimentation were the main reasons for destabilization. By increasing the concentrations of PGPR and magnesium chloride, TSI values of W/O emulsions decreased and therefore W/O emulsions became more stable with respect to coalescence. The stabilization mechanism was attributed to the decrease of emulsion droplets and the reduction in interfacial tension. Besides, interfacial viscoelastic measurements between soybean oil and water were conducted. The results indicated that stabilizing effect of PGPR and magnesium salt was not due to the rheological properties of interfacial film. The viscoelastic parameters of interfacial film increased at a lower concentration of magnesium salt (below 2%) while further increasing the concentration of magnesium salt to 6% led to a slight decrease of interfacial viscoelastic parameters. Increasing the concentration of PGPR from 0.5% to 2% led to a reduction in viscoelastic parameters.

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朱巧梅,韓湘,酈金龍,殷麗君.乳化劑與內(nèi)水相鎂鹽濃度對油包水乳液穩(wěn)定性的影響[J].農(nóng)業(yè)機械學報,2015,46(8):217-223. Zhu Qiaomei, Han Xiang, Li Jinlong, Yin Lijun. Influence of Concentrations of Emulsifier and Magnesium Salt Contained in Internal Phase on Stability of W/O Emulsions[J]. Transactions of the Chinese Society for Agricultural Machinery,2015,46(8):217-223.

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  • 收稿日期:2014-09-12
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  • 在線發(fā)布日期: 2015-08-10
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