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熱解溫度對(duì)生物質(zhì)炭性質(zhì)及其在土壤中礦化的影響
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“十二五”國(guó)家科技支撐計(jì)劃資助項(xiàng)目(2012BAD14B11)和國(guó)家高技術(shù)研究發(fā)展計(jì)劃(863計(jì)劃)資助項(xiàng)目(2011AA100504)


Characteristics and Mineralization in Soil of Apple-derived Biochar Producecd at Different Temperatures
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    摘要:

    以蘋(píng)果樹(shù)修剪的枝條為原料,分別在300,、400、500,、600℃條件下熱解制備生物質(zhì)炭,在采用掃描電鏡,、紅外光譜,、物理化學(xué)吸附儀等手段研究其性質(zhì)、結(jié)構(gòu)差異的基礎(chǔ)上,,通過(guò)培養(yǎng)試驗(yàn)研究不同溫度制備生物質(zhì)炭的礦化特征及其對(duì)土壤有機(jī)碳組分的影響,。結(jié)果表明,隨著熱解溫度的升高,,生物質(zhì)炭的碳含量,、比表面積及堿性官能團(tuán)的含量增加,O,、H及H/C、O/C和酸性官能團(tuán),、總官能團(tuán)的含量則降低,,生物質(zhì)炭的芳香族結(jié)構(gòu)加強(qiáng),穩(wěn)定性升高,。添加生物質(zhì)炭可以增加土壤呼吸速率,、微生物量碳(MBC)及可溶性有機(jī)碳(DOC)的含量,且隨著添加比例的增加而增加,,但隨著熱解溫度的升高而降低,。生物質(zhì)炭的礦化率隨著熱解溫度升高和添加比例增加而降低。利用雙庫(kù)模型揭示了生物質(zhì)炭對(duì)土壤活性碳庫(kù),、惰性碳庫(kù)及其分解速率的影響,。施用生物質(zhì)炭后土壤有機(jī)碳的半衰期在24.09~44.76a之間,且隨生物質(zhì)炭制備溫度升高而增大,??紤]到生物質(zhì)炭制備過(guò)程中有機(jī)碳的損失,且從提升土壤有機(jī)碳含量方面考慮,,500℃為制備蘋(píng)果枝條生物質(zhì)炭的最佳溫度,。

    Abstract:

    The aim of this study was to investigate the influence of pyrolysis temperature on the physic-chemical properties of biochar, and the effect of biochar addition on carbon contents of soil organic matter fractions and carbon mineralization characteristics. Biochars were produced by fast pyrolysis of apple tree twigs at 300, 400, 500 and 600℃, respectively. Characterizations of biochars were determined by elemental analysis, Brunauer—Emmett—Teller (BET) for surface area, scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy. Four kinds of biochar were added to soils at five application rates as soil only (control), soil+0.5% biochar, soil+1% biochar, soil+2% biochar and soil+3% biochar, which were incubated at 25℃ in lab. Carbon mineralization was analyzed by alkali absorption of CO2 released periodically over 180d. Soil samples were analyzed for microbial biomass carbon (MBC) and soil dissolved organic carbon (DOC). The results showed that the generated biochars contained 62.20%~80.01% of carbon (C), 2.72%~5.18% of hydrogen (H) and 15.99%~30.94% of oxygen (O). The BET surface area was 2.35~107.76m2/g, basic functional groups were 0.11~0.40mmol/g and acidic functional groups were 0.44~1.16mmol/g. The increasing temperature (from 300℃ to 600℃) increased biochar C content, BET surface area and basic functional groups, while decreased the content of O and H, H/C and O/C ratio, acidic functional groups and total functional groups. Soil respiration, MBC and DOC were increased by biochar application. As pyrolysis temperature increased and biochar application rate decreased, soil respiration, MBC and DOC decreased in all soils. The mineralization of biochar C decreased significantly (P<005) from 7.86% to 0.60% when pyrolysis temperature increased from 300℃ to 600℃. A doubleexponential equation was used to describe C mineralization kinetics and curve fitting was performed to mathematically define the size and turnover rate of two C source pools (labile and stable). The size of labile pool (A1) varied from 0.31g/kg to 0.94g/kg, while the size of stable pool (A2) varied from 6.88g/kg to 30.82g/kg. The decreased mineralization rates of the labile and stable pools (k1 and k2) were resulted from the increased pyrolysis temperature and the decreased biochar application rates. Halflife of C in soil varied between 24.09a and 44.76a and increased with the increase of pyrolysis temperature and biochar application rates. Conclusively, pyrolysis temperature had important effect on the physico-chemical properties of biochar and therefore resulting in different stabilities of soil organic matter. Considering the carbon loss in the process of preparing biochar, 500℃ would be the optimal temperature for preparing apple-derived biochar due to the most significant promotion of soil organic carbon.

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趙世翔,姬強(qiáng),李忠徽,王旭東.熱解溫度對(duì)生物質(zhì)炭性質(zhì)及其在土壤中礦化的影響[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2015,46(6):183-192,200. Zhao Shixiang, Ji Qiang, Li Zhonghui, Wang Xudong. Characteristics and Mineralization in Soil of Apple-derived Biochar Producecd at Different Temperatures[J]. Transactions of the Chinese Society for Agricultural Machinery,2015,46(6):183-192,200.

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  • 收稿日期:2014-06-16
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  • 在線發(fā)布日期: 2015-06-10
  • 出版日期: 2015-06-10
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