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油菜秸稈燃燒特性及其主要氣體產(chǎn)物表征分析
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公益性行業(yè)(農(nóng)業(yè))科研專項資助項目(201003063)和教育部新世紀優(yōu)秀人才支持計劃資助項目(NCET-12-0524)


Quantitative Characterization of Rape Straw Combustion and Gas Emissions Using TG/DSC-FTIR-MS Technology
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    摘要:

    以油菜秸稈為研究對象,,基于同步熱分析、紅外和質(zhì)譜(TG/DSC-FTIR-MS)聯(lián)用技術(shù),,系統(tǒng)研究了恒定升溫速率下不同氣流速率和樣品粒徑油菜秸稈的動態(tài)燃燒特性,,并對其主要氣體產(chǎn)物進行了定性和定量表征分析,。研究結(jié)果表明:油菜秸稈在設定的不同因素水平條件下燃燒特性無顯著差異,,在燃燒階段均析出較大量氣體,主要包括大量的CO2以及少量NOx,、SO2,、HCl等氣體,產(chǎn)生量依次遞減,,且氣體隨時間釋放特性與熱失重速率特性具有一致的對應關(guān)系,。基于TG/DSC-FTIR-MS聯(lián)用技術(shù)定量模擬研究油菜秸稈動態(tài)燃燒特性和氣體排放特性,,可為油菜秸稈環(huán)境友好型高效能源化利用提供方法學和基礎數(shù)據(jù)支撐,。

    Abstract:

    This paper took rape straw as the research object. Based on the TG/DSC-FTIR-MS technology, the dynamic characteristics of combustion were studied systematically with different air flow rates and sample particle sizes. And the qualitative and quantitative characterization analysis of main gas emissions was conducted. The results showed that there was no significant difference on combustion characteristics under different factor-levels. During each burning process, most gas escaped, including a larger amount of CO2 and a smaller amount of alkane gases such as NOx, SO2 and HCl with a diminishing magnitude. Also intensity curves of gases released corresponded to the characteristics of thermal weight loss rate. Quantitative study on the dynamic characteristics of combustion and gas emissions using TG/DSC-FTIR-MS technology could provide basic data and methodological support for the rape straw as environmentally friendly renewable energy.

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馬秋林,韓魯佳,黃光群.油菜秸稈燃燒特性及其主要氣體產(chǎn)物表征分析[J].農(nóng)業(yè)機械學報,2014,45(S1):196-201. Ma Qiulin, Han Lujia, Huang Guangqun. Quantitative Characterization of Rape Straw Combustion and Gas Emissions Using TG/DSC-FTIR-MS Technology[J]. Transactions of the Chinese Society for Agricultural Machinery,2014,45(S1):196-201.

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  • 收稿日期:2014-07-28
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  • 在線發(fā)布日期: 2014-11-15
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