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油菜秸稈真空熱解蒸氣在線催化提質研究
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國家自然科學基金資助項目(51276085),、江蘇省自然科學基金資助項目(BK2011488),、江蘇省高校優(yōu)勢學科建設資助項目(蘇政辦發(fā)\[2011\]6號),、江蘇省重點實驗室開放課題資助項目(QK13005)和江蘇省博士研究生科研創(chuàng)新資助項目(KYLX_1039)


Catalytic Upgrading of Pyrolytic Vapors from Rape Straw Vacuum Pyrolysis
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    摘要:

    以HZSM—5分子篩為催化劑,,在兩段式反應器上對油菜秸稈真空熱解產(chǎn)生的蒸氣進行了在線催化提質研究,??疾炝舜呋瘻囟?、催化劑用量和HZSM—5硅鋁比對產(chǎn)物產(chǎn)率的影響,;并以油相產(chǎn)物產(chǎn)率為指標,,采用響應面法對工藝參數(shù)進行了優(yōu)化,,并對在最優(yōu)條件下制取的油相和水相產(chǎn)物進行了理化特性分析。研究結果表明,,催化溫度,、催化劑用量和硅鋁比對產(chǎn)物產(chǎn)率影響顯著;獲得最高油相產(chǎn)率的工藝參數(shù)為:催化溫度為491.0℃,、催化劑用量為33.2g(生物質與催化劑質量比為0.301),、硅鋁比為53,此時,,油相產(chǎn)率達9.80%,,與預測值9.90%較為接近;油相產(chǎn)物的H/C摩爾比,、pH值和高位熱值分別為1.518,、5.15和33.80MJ/kg,可用作動力機械燃料,;水相產(chǎn)物(干基)的H/C摩爾比和高位熱值分別為1.269和29.69MJ/kg,,同樣具有較高的燃料品質。

    Abstract:

    The vapors directly catalyzed from vacuum pyrolysis of rape straw was investigated over HZSM—5 in a two-stage fixed-bed reactor to determine the effects of operating parameters on the product yields, including catalyzing temperature, biomass to catalyst mass ratio, and catalyst Si/Al ratio. The optimization of the oil phase yield was further conducted by employing response surface methodology (RSM). The statistical analysis showed that the operating parameters significantly affected the product yields. The optimal conditions for the maximum oil phase yield were obtained at catalyzing temperature of 491.0℃, biomass to catalyst mass ratio of 0.301, and catalyst Si/Al ratio of 53. Confirmation runs gave 9.80% of oil phase yield compared with 9.90% of predicated value. The upgraded bio-oil consisted of separable oil and aqueous phases. The H/C molar ratio, pH value and higher heat value (HHV) of the oil phase were 1.518, 5.15 and 33.80MJ/kg, respectively. It showed that the oil phase had a higher yield and the qualities, which can be used as an engine fuel. The H/C molar ratio and HHV of the aqueous phase (dry basis) were 1.269 and 29.69MJ/kg, respectively. The aqueous phase also had a high fuel value. 

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樊永勝,蔡憶昔,李小華,俞寧,尹海云.油菜秸稈真空熱解蒸氣在線催化提質研究[J].農(nóng)業(yè)機械學報,2014,45(12):234-240. Fan Yongsheng, Cai Yixi, Li Xiaohua, Yu Ning, Yin Haiyun. Catalytic Upgrading of Pyrolytic Vapors from Rape Straw Vacuum Pyrolysis[J]. Transactions of the Chinese Society for Agricultural Machinery,2014,45(12):234-240.

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  • 收稿日期:2013-12-16
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  • 在線發(fā)布日期: 2014-12-10
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