ass日本风韵熟妇pics男人扒开女人屁屁桶到爽|扒开胸露出奶头亲吻视频|邻居少妇的诱惑|人人妻在线播放|日日摸夜夜摸狠狠摸婷婷|制服 丝袜 人妻|激情熟妇中文字幕|看黄色欧美特一级|日本av人妻系列|高潮对白av,丰满岳妇乱熟妇之荡,日本丰满熟妇乱又伦,日韩欧美一区二区三区在线

NiO/HZSM-5催化改性生物油模擬物研究
CSTR:
作者:
作者單位:

作者簡(jiǎn)介:

通訊作者:

中圖分類號(hào):

基金項(xiàng)目:

中國(guó)博士后科學(xué)基金資助項(xiàng)目(2012M520698)、農(nóng)業(yè)部公益性行業(yè)專項(xiàng)資助項(xiàng)目(201003063-06),、黑龍江省博士后基金資助項(xiàng)目(LBH-Z12031),、黑龍江省教育廳科學(xué)技術(shù)研究資助項(xiàng)目(12531002)和東北農(nóng)業(yè)大學(xué)博士啟動(dòng)基金資助項(xiàng)目(2012RCB97)


Model Component of Bio-oil Upgrading by NiO/HZSM5 Catalyst
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 圖/表
  • |
  • 訪問(wèn)統(tǒng)計(jì)
  • |
  • 參考文獻(xiàn)
  • |
  • 相似文獻(xiàn)
  • |
  • 引證文獻(xiàn)
  • |
  • 資源附件
  • |
  • 文章評(píng)論
    摘要:

    以HZSM-5為載體,,通過(guò)浸漬法制備不同NiO負(fù)載量的NiO/HZSM-5催化劑并進(jìn)行表征,,發(fā)現(xiàn)負(fù)載量為8%的催化劑表面形貌相對(duì)平整,,比表面積,、酸位等特性較理想,。通過(guò)生物油模擬物催化試驗(yàn)對(duì)催化劑性能進(jìn)行評(píng)價(jià),試驗(yàn)結(jié)果表明負(fù)載量和反應(yīng)溫度都對(duì)催化劑活性有明顯影響,。在反應(yīng)溫度為400℃時(shí),,負(fù)載量為8%的催化劑使模擬物中甲苯和愈創(chuàng)木酚具有較好的轉(zhuǎn)化率,分別達(dá)到83%和88%,;較HZSM-5催化的情況分別提高60%和70%,。改性后生物油的熱值也可增加約30%。負(fù)載物NiO的加入使催化劑表面強(qiáng)酸位降低約45%,,同時(shí)提高了催化劑的穩(wěn)定性和抗積碳能力,,延長(zhǎng)了催化劑使用壽命,其中8-ZSM-5催化劑在反應(yīng)6h后仍保持較高活性,。

    Abstract:

    NiO/HZSM-5 catalysts with different NiO contents were prepared by impregnation method and their property was investigated. The surface performance tests showed taht the catalyst with 8% loading metal (8-ZSM-5) had satisfied surface morphology and structure. The catalytic activity of NiO/HZSM-5 catalyst was evaluated via the experimental study on catalytic bio-oil model in a self made biomass continuous pyrolysis system. The results showed that the reaction activities of the catalysts were greatly influenced by the NiO content and the catalytic temperature. When the reaction temperature was 400℃ and catalyst loading metal was 8%,,the catalyst made the percent conversion of the toluene and guaiacol reach 80% and 85% respectively, which increased 60% and 70% compared with only HZSM-5 catalyst acting. The heat value of upgrading bio-oil model could increase 30% as well. Meanwhile, the addition of NiO decreased the Bronsted acidity by 45%, and improved anti-carbon ability and stability of catalyst, and the lifetime of the catalyst was extented as well. The 8-ZSM-5 catalyst kept the high catalysis activity after 6h reaction.

    參考文獻(xiàn)
    相似文獻(xiàn)
    引證文獻(xiàn)
引用本文

秦麗元,孫焱,蔣恩臣,羅立娜. NiO/HZSM-5催化改性生物油模擬物研究[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2014,45(8):206-213. Qin Liyuan, Sun Yan, Jiang Enchen, Luo Lina. Model Component of Bio-oil Upgrading by NiO/HZSM5 Catalyst[J]. Transactions of the Chinese Society for Agricultural Machinery,2014,45(8):206-213.

復(fù)制
分享
文章指標(biāo)
  • 點(diǎn)擊次數(shù):
  • 下載次數(shù):
  • HTML閱讀次數(shù):
  • 引用次數(shù):
歷史
  • 收稿日期:2014-04-15
  • 最后修改日期:
  • 錄用日期:
  • 在線發(fā)布日期: 2014-08-10
  • 出版日期:
文章二維碼