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豬籠草內(nèi)表面微觀結(jié)構(gòu)及其浸潤性研究
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國家自然科學基金資助項目(51290292)


Microstructure and Wettability Character of Nepenthes’ Pitcher Surfaces
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    摘要:

    測量了豬籠草內(nèi)表面各部位的接觸角,,發(fā)現(xiàn)超滑區(qū)疏水,,最大接觸角(150±2)°,;超滑區(qū)和消化區(qū)有明顯的浸潤分界線,;消化區(qū)親水,,最低接觸角(16±2)°,。研究發(fā)現(xiàn)超滑區(qū)呈微米級新月形,、納米級片狀的復合結(jié)構(gòu),,消化區(qū)呈微米級凹坑,、網(wǎng)狀褶皺的復合結(jié)構(gòu),。結(jié)合化學處理和直接復制成形分析了內(nèi)表面微結(jié)構(gòu)和成分對浸潤性的影響。結(jié)果表明超滑區(qū)的納米級片狀,、網(wǎng)狀蠟質(zhì)結(jié)構(gòu)對其超疏水特性起決定作用,,消化區(qū)的接近超親水特性主要與其表面物質(zhì)成分有關(guān),兩個區(qū)域浸潤性的大跨度變化是化學組成和表面形貌共同作用的結(jié)果,。

    Abstract:

    Nepenthes’ pitchers are marvelous leaves working as insect traps which is mainly caused by the inner surfaces. While the wettability of the inner pitcher surface is still a lack of in-depth research. Through various measuremtns of the contact angle of Nepenths’ pitcher surfaces, it was found that the slippery zone is hydrophobic with the maximum contact angle (150±2)° and the digestive zone is hydrophilic with the minimum contact angle (16±2)°, and there exists an obvious wettability dividing line between slippery zone and digestive zone. Micro- and nanoscale hierarchical structures are present on the slippery zone, while a microscale hierarchical structure is present on the digestive zone. The effect of the material composition and microstructure of the inner surfaces on wettability were analysed through chemical treatment and bio-replication. The results show that hydrophobic of the slippery zone is mainly caused by the wax on pitcher surface and hydrophilic of the digestive zone may be caused by some kinds of hydrophilic materials. The large span of wettability between slippery zone and digestive zone is depend on both its chemical composition and its surface morphology. This research may provide a reference for the design of slippery surfaces.

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張鵬飛,張德遠,陳華偉.豬籠草內(nèi)表面微觀結(jié)構(gòu)及其浸潤性研究[J].農(nóng)業(yè)機械學報,2014,45(1):341-345. Zhang Pengfei, Zhang Deyuan, Chen Huawei. Microstructure and Wettability Character of Nepenthes’ Pitcher Surfaces[J]. Transactions of the Chinese Society for Agricultural Machinery,2014,45(1):341-345.

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  • 收稿日期:2013-01-22
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  • 在線發(fā)布日期: 2014-01-03
  • 出版日期: 2014-01-03
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