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雪蓮果吸附等溫線及熱力學(xué)性質(zhì)研究
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國家自然科學(xué)基金資助項(xiàng)目(31171708)和山東理工大學(xué)青年教師發(fā)展支持計劃資助項(xiàng)目(110033)


Moisture Sorption Isotherm and Thermodynamic Properties of Yacon
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    摘要:

    采用靜態(tài)稱量法研究了雪蓮果(包括純雪蓮果粉(YP)和按總固形物含量比例為1〖DK〗∶1添加麥芽糊精(MD)的雪蓮果粉(YP-MD))在溫度15,、25,、35℃時的吸附等溫線;采用7種常用數(shù)學(xué)模型擬合試驗(yàn)數(shù)據(jù),得到用于描述雪蓮果吸附特性的最適模型,;探討了雪蓮果的熱力學(xué)性質(zhì)(如凈等量吸附熱,、微分熵,、熵焓互補(bǔ)和擴(kuò)張壓力)及添加MD對雪蓮果水分吸附特性和熱力學(xué)性質(zhì)的影響,。結(jié)果表明,雪蓮果水分吸附特性為Ⅲ型等溫線,,GAB模型為描述雪蓮果水分吸附特性的最適模型,。YP和YP-MD的平衡含水率隨著水分活度aw的增加而增加。添加MD降低了雪蓮果的單分子含水率M0,。溫度15~35℃時,,YP和YP-MD的M0范圍分別為15.04%~9.04%和8.80%~5.91%。雪蓮果的凈等量吸附熱qst和微分熵Sd隨著含水率的增加而降低,,YP和YP-MD的含水率由6.33%增加至75.29%時,,其qst分別由67.44kJ/mol和66.17kJ/mol降低至62.23kJ/mol和62.12kJ/mol,YP的Sd總高于YP-MD,。雪蓮果的擴(kuò)張壓力隨著aw的增加而升高,,隨著溫度的升高而降低;而在相同aw和溫度下,,YP的擴(kuò)張壓力總高于YP-MD,。YP和YP-MD的水分吸附過程均為熵驅(qū)動,。

    Abstract:

    Moisture sorption isotherms of pure yacon powder (YP) and yacon powder with maltodextrin addition (YP-MD) (total solids ratio of yacon〖DK〗∶maltodextrin=1∶1) were determined at different temperatures (15, 25 and 35℃) by static gravimetric method. The best model for describing yacon adsorption characteristic was determined through seven models fitting analyses. Thermodynamic properties, namely net isosteric heat of sorption, differential entropy, enthalpy-entropy compensation and spreading pressure, were determined from sorption isotherm data of yacon. The effect of maltodextrin (MD) on the sorption characteristics and thermodynamic properties were also discussed. The results show that the sorption behaviour of yacon follows a type Ⅲ isotherm; GAB model is the best fit one for describing yacon adsorption characteristic for both YP and YP-MD. Equilibrium moisture content of YP and YP-MD increases with water activity (aw). Addition of MD decreases the monolayer moisture content (M0) of yacon. When temperature ranges from 15℃ to 35℃, the M0 of YP and YP-MD ranges from 15.04% to 9.04%, 8.80% to 5.91%, respectively. The net isosteric heat of sorption (qst) and differential entropy (Sd) decreases with the increasing of moisture contents. The qst of YP and YP-MD decreases from 67.44kJ/mol to 62.23kJ/mol, and 66.17kJ/mol to 62.12kJ/mol as the moisture content increases from 6.33% to 75.29%. The value of Sd of YP is always higher than that of YP-MD. The spreading pressure of YP and YP-MD increases with increasing aw, and decreases with increasing temperature. The value of spreading pressure of YP is always higher than that of YP-MD at fixed aw and temperature. Through this study, a conclusion can be drawn at last that the driving force of moisture sorption for PY and PY-MD is entropy.

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石啟龍,趙亞,馬占強(qiáng).雪蓮果吸附等溫線及熱力學(xué)性質(zhì)研究[J].農(nóng)業(yè)機(jī)械學(xué)報,2014,45(1):214-221. Shi Qilong, Zhao Ya, Ma Zhanqiang. Moisture Sorption Isotherm and Thermodynamic Properties of Yacon[J]. Transactions of the Chinese Society for Agricultural Machinery,2014,45(1):214-221.

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  • 收稿日期:2013-08-06
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  • 在線發(fā)布日期: 2014-01-03
  • 出版日期: 2014-01-03
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