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草漿黑液半焦直接苛化水蒸氣氣化特性研究
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國家自然科學基金資助項目(51176195)和“十二五”國家科技支撐計劃資助項目(2012BAA09B03)


Gasification Characteristics of Wheat Straw Black Liquor Char Steam with Direct Causticization
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    摘要:

    采用管式爐在750~900℃內進行了草漿黑液半焦水蒸氣氣化實驗,考察了溫度,、苛化劑TiO2對氣體產(chǎn)物及固體產(chǎn)物的影響,;采用熱重分析儀在850℃下進行了半焦的水蒸氣氣化實驗,,探究了TiO2對半焦熱失重特性的影響,。結果表明:在750~900℃內,,TiO2的添加使得氣體產(chǎn)物中CO2增加約5%,、H2減少約5%,,碳轉化率上升約10%,產(chǎn)氣熱值下降約7%,;TiO2可避免氣化過程中熔融物的生成,;隨著溫度的升高,固體產(chǎn)物中無機鹽的種類未發(fā)生變化,;TiO2與半焦中的Na2CO3反應生成Na2O·nTiO2,,與Na2SiO3結合生成Na2TiSiO5,改變了元素Na與Si的存在形態(tài),。

    Abstract:

    The steam gasification of wheat straw black liquor char (BLC) was studied in a laboratory-scale tube furnace at temperature from 750℃ to 900℃. The impacts of temperature and causticizing agent TiO2 on characteristics of gas and solid product during gasification process were investigated. Influence of TiO2 on weight loss characteristics of BLC was also studied by thermo gravimetric analyzer at temperature 850℃.Results showed that at temperature from 750℃ to 900℃, with TiO2 addition, the relative concentration of CO2 increases by about 5% while the relative concentration of H2 decreases by about 5% in gas product, at the same time the gas heating value reduces by about 7%; however, carbon conversion rate increases by about 10% without melting of char in the gasification process;temperature has no significant effect on the composition of the solid product. Furthermore, TiO2 changes the partition of Na and Si in char. TiO2 not only reacts with Na2CO3 to form Na2O〖DK〗·nTiO2, but also combines with Na2SiO3 to generate Na2TiSiO5.

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王貴金,袁洪友,郭大亮,周肇秋,陰秀麗,吳創(chuàng)之.草漿黑液半焦直接苛化水蒸氣氣化特性研究[J].農業(yè)機械學報,2014,45(1):150-154. Wang Guijin, Yuan Hongyou, Guo Daliang, Zhou Zhaoqiu, Yin Xiuli, Wu Chuangzhi. Gasification Characteristics of Wheat Straw Black Liquor Char Steam with Direct Causticization[J]. Transactions of the Chinese Society for Agricultural Machinery,2014,45(1):150-154.

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  • 收稿日期:2013-01-21
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  • 在線發(fā)布日期: 2014-01-03
  • 出版日期: 2014-01-03
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