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鈉離子對(duì)蘆葦硫酸鹽黑液木素CO2氣化特性的影響
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國(guó)家自然科學(xué)基金資助項(xiàng)目（51176195、21176095）


Influence of Sodium Cation on Characteristics of CO2 Gasification of Lignin from Reed Kraft Black Liquor
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    摘要:

    為考察鈉離子對(duì)蘆葦硫酸鹽黑液木素CO2氣化特性的影響,采用熱重—紅外技術(shù)分別對(duì)水溶木素(WSL),、水不溶木素(WIL)和硫酸鹽黑液(KBL)的失重特性進(jìn)行了分析,。由于鈉離子的存在,，在整個(gè)反應(yīng)過(guò)程中WSL和KBL的熱重（TG）曲線相似,。雖然WSL和WIL的化學(xué)結(jié)構(gòu)相似,，但是它們的CO2氣化反應(yīng)性卻不同,。在WSL的CO2氣化過(guò)程中,，木素化學(xué)結(jié)構(gòu)上的鈉離子對(duì)CO的形成具有控制作用,。

    Abstract:

    The water-insoluble lignin (WIL), water-soluble lignin (WSL) and kraft black liquor (KBL) were performed on a thermogravimetry coupled with Fourier transform infrared spectrometry (TG—FTIR) to study the impact of sodium cation on lignin CO2 gasification, respectively. The TG profiles of the WSL and KBL were analogical during the whole reaction owing to the presence of sodium cation. The WIL and WSL had similar chemical structure, but there were different reactivity of CO2 gasification. Sodium cation on lignin structure had a control effect on the formation of CO in the CO2 gasification of WSL.

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楊卿,陰秀麗,吳創(chuàng)之,武書(shū)彬,郭大亮.鈉離子對(duì)蘆葦硫酸鹽黑液木素CO2氣化特性的影響[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2013,44(3):137-141. Yang Qing, Yin Xiuli, Wu Chuangzhi, Wu Shubin, Guo Daliang. Influence of Sodium Cation on Characteristics of CO2 Gasification of Lignin from Reed Kraft Black Liquor[J]. Transactions of the Chinese Society for Agricultural Machinery,2013,44(3):137-141.

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  • 在線發(fā)布日期: 2013-02-25
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