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丙酸預處理小麥秸稈的纖維素水解動力學
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“十一五”國家科技支撐計劃資助項目(2007BAD66B04)


Kinetics Hydrolysis of Cellulose of Wheat Straw Pretreated with Propionic Acid
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    摘要:

    利用丙酸法預處理小麥秸稈，測定了不同溫度下反應產(chǎn)物中葡萄糖質(zhì)量濃度，并根據(jù)Saeman模型,，計算得到了纖維素水解和葡萄糖降解的動力學數(shù)據(jù),，其活化能分別為6.5086×104J/mol 和5.6223×104J/mol。動力學分析表明：纖維素水解反應速度快,，但是生成的葡萄糖容易發(fā)生降解,；該模型的最優(yōu)化反應條件為80℃和176min，實驗得到的葡萄糖質(zhì)量濃度為8.89g/L,，與模型預測結(jié)果偏差很小,。

    Abstract:

    The cellulose from wheat straw was pretreated with propionic acid, and the content of glucose at different reaction temperatures was determined. Based on the Saeman model, the kinetics data of cellulose hydrolysis and glucose degradation were calculated. The activation energy was 6.5086×104J/mol and 5.6223×104J/mol, respectively. The analysis results indicated that cellulose has a faster hydrolysis rate, and the glucose formed is easy to degrade. The optimum reaction conditions are 80℃ and 176min, and the content of glucose reached 8.89g/L. The adequacy of the model for predicting is verified effectively by the validation．

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田龍,馬曉建.丙酸預處理小麥秸稈的纖維素水解動力學[J].農(nóng)業(yè)機械學報,2012,43(9):111-115. Tian Long, Ma Xiaojian. Kinetics Hydrolysis of Cellulose of Wheat Straw Pretreated with Propionic Acid[J]. Transactions of the Chinese Society for Agricultural Machinery,2012,43(9):111-115.

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  • 在線發(fā)布日期: 2012-09-04
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