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生物質(zhì)流化床富氧-水蒸氣氣化制備合成氣研究
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國(guó)家高技術(shù)研究發(fā)展計(jì)劃(863計(jì)劃)資助項(xiàng)目(2007AA05Z410,、2009AA05Z434)和中國(guó)科學(xué)院知識(shí)創(chuàng)新工程重要方向項(xiàng)目(KGCX2-YW-329)


Biomass Oxygen Enriched-steam Gasification in an Atmospheric Fluidized Bed for Syngas Production
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    摘要:

    使用不同含水率的木粉為原料,以180~270kg/h的進(jìn)料速度在內(nèi)徑0.5m、高9m的常壓流化床氣化爐上進(jìn)行了富氧-水蒸氣氣化制備合成氣實(shí)驗(yàn),??疾炝水?dāng)量比,、水蒸氣配比,、二次風(fēng)以及原料含水率對(duì)氣化溫度,、燃?xì)饨M分,、低位熱值,、氣體產(chǎn)率、氣化效率和碳轉(zhuǎn)化率等參數(shù)的影響,。結(jié)果顯示:當(dāng)量比為0.25~0.27之間,,水蒸氣配比0.4時(shí),H2含量最高可達(dá)28.7%,,H2/CO為0.94,,燃?xì)鉄嶂?.9MJ/m3,氣化效率大于75%, 碳轉(zhuǎn)化率大于97%,;提高二次風(fēng)比率可明顯降低焦油含量,,在總當(dāng)量比0.29、二次風(fēng)比率25%時(shí)焦油含量為49mg/m3,;原料水分增加,,氣體質(zhì)量下降,含水率以不超過(guò)20%為宜,。

    Abstract:

    Biomass gasification with steamoxygen enriched air in an atmospheric fluidized bed gasifier was studied. The gasifier was 9m high with the bed diameter of 0.5m. Sawdust with different moisture contents was used as feedstock, and it was fed into the gasifier at flow rates of 180~270kg/h. The effects of equivalence ratio, steam to biomass ratio, secondary flow ratio and feedstock moisture on the bed temperature, gas compositions, tar content, lower heating values, gas yield, carbon conversion efficiency and cold gas efficiency were investigated. The results showed under the operating conditions of ER is 0.25~0.27 and S/B=0.4, the following syngas was obtained: H2 content of 28.7%, H2/CO ratio of 0.94, low heating value of 9.9MJ/m3, cold gas efficiency was more than 75%, carbon conversion efficiency was more than 97%; a second flow ratio of 25% at the ER of 0.29 can significantly reduce the tar content to 49mg/m3, but hardly improve the quality of the gas produced; the rise of the feedstock moisture content caused a significant increase in CO2 content and a reduction in H2 and CO contents, and the moisture content is expected not to exceed 20%. 

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蘇德仁,周肇秋,謝建軍,朗林,陰秀麗,吳創(chuàng)之.生物質(zhì)流化床富氧-水蒸氣氣化制備合成氣研究[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2011,42(3):100-104. Su Deren, Zhou Zhaoqiu, Xie Jianjun, Lang Lin, Yin Xiuli, Wu Chuangzhi. Biomass Oxygen Enriched-steam Gasification in an Atmospheric Fluidized Bed for Syngas Production[J]. Transactions of the Chinese Society for Agricultural Machinery,2011,42(3):100-104.

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