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基于OSC和PLS的土壤有機(jī)質(zhì)近紅外光譜測(cè)定
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    摘要:

    分析了經(jīng)過簡單處理的土壤樣本光譜特性,,將正交信號(hào)校正與偏最小二乘算法回歸相結(jié)合,建立了土壤光譜特性與土壤有機(jī)質(zhì)含量之間的定量分析模型,。結(jié)果表明,,正交信號(hào)校正可以消除噪聲信息對(duì)土壤有機(jī)質(zhì)含量預(yù)測(cè)的影響,,預(yù)測(cè)樣本的預(yù)測(cè)相關(guān)系數(shù)達(dá)到0.893,、標(biāo)準(zhǔn)偏差為0.051%,、預(yù)測(cè)標(biāo)準(zhǔn)差為0.050%,;而不采用正交信號(hào)校正建立定量分析模型的對(duì)應(yīng)參數(shù)分別為

    Abstract:

    0.818,、0.069%和0.085%,。Spectral properties of simply treated soil samples were analyzed by using Nicolet intelligent Fourier transform (FT) infrared spectrum. A new pretreatment method-orthogonal signal correction (OSC) was presented to eliminate the influence of the noise on soil organic matter (SOM) content prediction. Partial least square (PLS) analysis has been used to build prediction models with calibration data of 67 samples. The remaining 20 samples were used to validate the models. The result showed that OSC-PLS could improve the prediction ability greatly. The correlation coefficient is 0.893, standard error of prediction (SEP) is 0.051%, and root mean standard error of prediction (RMSEP) is 0.050% respectively. 

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宋海燕,何勇.基于OSC和PLS的土壤有機(jī)質(zhì)近紅外光譜測(cè)定[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2007,38(12):113-115.[J]. Transactions of the Chinese Society for Agricultural Machinery,2007,38(12):113-115.

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